Abstract
Two possible reactive sites (the oxo site and the Ru site) for water on a high-valent ruthenium(V) oxo complex were examined. Our results suggest that the reaction on the ruthenium (via a seven coordinate intermediate) has both a lower barrier and a product with a lower free energy than the product of addition at the oxo.
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Schedule a callMore From: Zeitschrift für Elektrochemie und angewandte physikalische Chemie
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