What in particle morphology determines the DLVO interaction energy between hematite particles in electrolyte solutions?

Abstract

The experimental stability of hematite particles (radius: ∼74 nm) dispersed in solutions of varying salinity deviates considerably from predictions based on the Derjaguin–Landau–Verwey–Overbeek (DLVO) theory. For untreated hematite particles, at pH = 6 and 10, the theoretical values could be matched to the experimental ones by modifying the particle radius used in calculations from 74 to 13 nm. For particles heat-treated at 350 °C for 1 h, the theoretical values at pH = 10 could also be matched to the experimental ones by modifying the particle radius to 7 nm. Atomic force microscopy measurements revealed that the radius of curvature for surface protrusions on the hematite particles was 14 nm on average for the untreated particles at pH = 6 and 10, which almost equals the aforementioned modified particle radius. For the heat-treated hematite particles at pH = 10, the average radius of curvature was 9 nm, which also matched the corresponding modified particle radius. Therefore, we argue that the interaction energy between hematite particles is governed by not the overall particle radius but the curvature radius for surface protrusions. This could account for the discrepancy between theory and experiment regarding the salinity-dependent stability ratio of these particle dispersions.