Abstract
We derive a theoretical expression of the second harmonic scattering signal in diluted electrolytes compared with bulk water. We show that the enhancement of the signal with respect to pure water observed recently for electrolytes at very low dilution in the micromolar range is a mere manifestation of the Debye screening that makes the infinite-range dipole-dipole solvent correlations in 1/ r3 disappear as soon as the ionic concentration becomes finite. In q space, this translates into a correlation function having a well known singular behavior around q = 0, which drives the observed ionic effects. We find that the signal is independent of the ion-induced long-range behavior of the function ⟨cos ϕ( r)⟩ that has been recently discussed. We find also that the enhancement depends on the experimental geometry and occurs only for in-plane polarization detection, as observed experimentally. On the contrary, the measured isotope effect between light and heavy water cannot be fully explained.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
