What Controls the Leaching of Magnesite with Concentrated Solutions of Hydrochloric or Nitric Acid?

Abstract

ABSTRACT The kinetics of the leaching of natural magnesite with hydrochloric or nitric acid has been studied. Relatively high values of the apparent activation energy (from 46.5 to 70.0 kJ mol−1), but especially the low values of the apparent reaction order for H+ cations, n , have shown that the whole process is controlled by the surface chemical reaction. The value of n decreases continuously with increasing activity of H+ cations in the range of pH 5 to −1.4. At pH < 2.6 there is a transition from the kinetic regime characterized by n ≅ 0.5 to another one with n close to zero.