Abstract
Using molecular dynamics simulation, we show that the vibrational relaxation lifetime of a diatomic in a two-dimensional supercritical rare-gas fluid exhibits the same unexpected plateau behavior as was observed experimentally for W(CO)6 in supercritical CO2 by Fayer and co-workers, and we link this behavior to average local solvent density enhancements arising from the solvent’s near-critical density fluctuations.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
