Wetting of AgCuTi alloys on quartz fiber reinforced composite modified by vertically aligned carbon nanotubes

Abstract

Due to the poor wettability of the AgCuTi alloy on the quartz fiber reinforced composite (QFSC), a reliable joining of the QFSC to itself or to other metals can be hardly achieved. In this study, vertically aligned carbon nanotube (VA-CNT) composed of multi-wall carbon nanotube (MWCNT) was synthesized on the QFSC surface by a plasma enhanced chemical vapor deposition method. As a result, the final contact angle decreased from 96.5° (without VA-CNT modification) down to 30.6° (with VA-CNT modification) at 870 °C with 10min holding duration. Besides, the reaction layers at the AgCuTi/QFSC interface transformed into continuous ones and the infiltration effects became more obvious after the VA-CNT modification. Finally, a possible mechanism how VA-CNT enhanced the wettability of the AgCuTi alloy on the QFSC surface was proposed. Defective sites on the MWCNT surface with a high chemical reactivity and the nanoscale capillary structure of the VA-CNT turned out to be the essential factors to promote the wetting process. This novel surface modification approach can offer new insights on addressing the wetting issues in composites preparation, brazing and soldering, etc..