Abstract

For the first time, the wettability and surface energy of parylene F were investigated. The results showed that parylene F had a hydrophobic surface with an eigen water contact angle of 104.7 ± 0.6°. We found that 3.5 μl probe liquid was an optimal value for the contact angle measurement of parylene F. Moreover, we found that the Lifshitz–van der Waals/acid–base approach was unsuitable for determining the surface energy of parylene F, whereas the Owens–Wendt–Kaelble approach and the limitless liquid–solid interface wetting system were compatible. The surface energy of parylene F was estimated to be 27.06 mJ/m2 (Owens–Wendt–Kaelble) and 40.41 mJ/m2 (Limitless liquid-solid interface wetting system). Furthermore, this investigation also provided a reference for the applications of empirical and physics-based semi-empirical approaches for the estimation of surface energy.

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