Abstract
The synthesis of a series of well-defined (N-heterocyclic carbene)PdCl2(azetidine) complexes are presented. The structures of all complexes were fully characterized by 1H-NMR and 13C-NMR, which supported the proposed structures. The molecular structures of all complexes were further determined by single-crystal X-ray diffraction. The catalytic activities of the obtained Pd-complexes were then evaluated in Suzuki-Miyaura, Sonogashira and Mizoroki-Heck coupling reactions.
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