Abstract
Unprecedented synthesis of multiblock poly(vinylidene fluoride) (PVDF, up to 16 300 g mol-1) with narrow-dispersity blocks (Đ = 1.26) mediated by a fluorinated cyclic xanthate via reversible addition-fragmentation chain transfer (RAFT) polymerization is reported. The as-synthesized multiblock PVDF was employed as a macroRAFT agent to prepare valuable multiblock copolymers with potential applications in emerging areas.
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