Abstract
Two series of o-diamidobenzenes, bearing long-chain alkyl substituted gallic ester groups, have been synthesised. The 3,4,5,6-unsubstituted amides 7 with a minimum chain length of C9 exhibited columnar rectangular mesophases of p2mm symmetry with Z = 2. The liquid crystalline phases spread over phase width of extremely wide temperature intervals from -50 to 118°C. However, the phase width slightly decreased with an increase in the length of alkyl substituents. Despite their very similar molecular structure, 1,2-dimethoxy-4,5-diamides 10 revealed a different packing behaviour in their mesophases, due to steric factors. The diamides 10 formed columnar rectangular mesophases with p2mm symmetry, but with Z = 3. In a comparison with unsubstituted analogues 7, compounds 10 displayed even broader mesophases (with temperature intervals up to 220°C).
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