Weathering and erosion in central Vietnam over the Holocene and Younger Dryas: Clay mineralogy and elemental geochemistry from the Vietnam Shelf, western South China Sea

Abstract

Clay mineralogy and elemental geochemistry of Core SO18401 on the Vietnam Shelf are used to reconstruct the history of weathering and erosion in central Vietnam over the past 13.2 ka. The variability of the clay species across the 13.2 ka BP together with the age model allows a subdivision into four temporal stages. Provenance analysis based on clay mineralogy indicates that small mountainous rivers in southern-central Vietnam are the major sources of terrigenous sediments on the central Vietnam Shelf. Smectite and kaolinite originated from the chemical weathering of Mesozoic and Neogene-Quaternary basaltic rocks and Paleo-Mesozoic felsic intrusive rocks, respectively, under warm and humid climate conditions; whereas illite and chlorite were mainly derived from physical weathering of Paleo-Mesozoic felsic intrusive rocks and Precambrian metamorphic rocks in central Vietnam. Accordingly, smectite/(illite + chlorite) ratio, together with elemental ratios of Al2O3/K2O, TiO2/Al2O3, and SiO2/Al2O3, can be utilized to reflect the relative importance between chemical weathering and physical weathering/erosion of the parent rocks in southern-central Vietnam. Higher smectite/(illite + chlorite) and Al2O3/K2O ratios indicate a more important role of chemical weathering, and higher TiO2/Al2O3 and SiO2/Al2O3 ratios suggest enhanced contribution of physical weathering and erosion. A combination of these mineralogical and elemental proxies allows the distinction of four stages of weathering and erosion evolution in southern-central Vietnam over the Holocene and Younger Dryas periods. Enhanced physical weathering and erosion took place during the periods ∼13.2–11.0 ka BP (Stage I) and ∼3.9–2.0 ka BP (Stage III), associated with relatively arid conditions. By contrast, strengthened chemical weathering occurred during the periods ∼11.0–3.9 ka BP (Stage II) and 2.0 ka BP to present (Stage IV), corresponding to more warm and humid climatic conditions. Our study suggests that the weathering and erosion history of southern-central Vietnam over the Holocene is mainly controlled by the East Asian monsoon climate.