Wear Behavior and Microstructure of Mg-Sn Alloy Processed by Equal Channel Angular Extrusion.

Jung-Hsuan Chen,Yen-Chen Shen,Chuen-Guang Chao,Tzeng-Feng Liu

doi:10.3390/ma10111315

Jung-Hsuan Chen, Yen-Chen Shen + Show 2 more

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https://doi.org/10.3390/ma10111315

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Abstract

Mg-5wt.% Sn alloy is often used in portable electronic devices and automobiles. In this study, mechanical properties of Mg-5wt.% Sn alloy processed by Equal Channel Angular Extrusion (ECAE) were characterized. More precisely, its hardness and wear behavior were measured using Vickers hardness test and a pin-on-disc wear test. The microstructures of ECAE-processed Mg-Sn alloys were investigated by scanning electron microscope and X-ray diffraction. ECAE process refined the grain sizes of the Mg-Sn alloy from 117.6 μm (as-cast) to 88.0 μm (one pass), 49.5 μm (two passes) and 24.4 μm (four passes), respectively. Meanwhile, the hardness of the alloy improved significantly. The maximum wear resistance achieved in the present work was around 73.77 m/mm3, which was obtained from the Mg-Sn alloy treated with a one-pass ECAE process with a grain size of 88.0 μm. The wear resistance improvement was caused by the grain size refinement and the precipitate of the second phase, Mg2Sn against the oxidation of the processed alloy. The as-cast Mg-Sn alloy with the larger grain size, i.e., 117.6 μm, underwent wear mechanisms, mainly adhesive wear and abrasive wear. In ECAE-processed Mg-Sn alloy, high internal energy occurred due to the high dislocation density and the stress field produced by the plastic deformation, which led to an increased oxidation rate of the processed alloy during sliding. Therefore, the oxidative wear and a three-body abrasive wear in which the oxide debris acted as the three-body abrasive components became the dominant factors in the wear behavior, and as a result, reduced the wear resistance in the multi-pass ECAE-processed alloy.

Highlights

Mg alloys are regarded as a material with great potential for high performance structural applications due to their low density, great mechanical properties, and good cast ability [1,2,3,4].Mg-Sn alloys in particular have attracted much attention because the melting point of the intermetallic phase, Mg2 Sn, in the Mg-Sn alloy (770 ◦ C) is much higher than that of the Mg17 Al12 phase in the Mg-Al alloy (462 ◦ C) [5,6]
We investigated the wear behavior of Mg-5wt.% Sn alloys, focusing on the alloys processed by Equal Channel Angular Extrusion (ECAE)
For the ECAE process, as-cast Mg-Sn alloy specimens were machined into a billet with dimensions of 15 mm × 15 mm × 50 mm via wire electrical discharge machining, and heated in the die for 20 min before the extrusion

Summary

Introduction

Mg alloys are regarded as a material with great potential for high performance structural applications due to their low density, great mechanical properties, and good cast ability [1,2,3,4].Mg-Sn alloys in particular have attracted much attention because the melting point of the intermetallic phase, Mg2 Sn, in the Mg-Sn alloy (770 ◦ C) is much higher than that of the Mg17 Al12 phase in the Mg-Al alloy (462 ◦ C) [5,6]. The high temperature mechanical properties of Mg-Sn alloys can be improved substantially. Liu and his coworkers [7] demonstrated the microstructure, tensile properties, and creep behavior of as-cast Mg-(1–10%) Sn alloys. Their experiment results indicated that the Mg-55wt.% Sn alloy had the greatest tensile and elongation. There has been much research on Mg-5wt.% Sn alloys focused on mechanical properties, high temperature performances, corrosion characteristics, creep properties, and so on [8,9,10,11]. Wear modes, and wear mechanism all should be considered when selecting suitable material for Materials 2017, 10, 1315; doi:10.3390/ma10111315 www.mdpi.com/journal/materials

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