Abstract
A weak interaction model has been used to examine the potential energy surfaces of weakly bound dimers, that include a hydrogen sulfide molecule. The comparison with corresponding water clusters shows certain structural similarities but significantly different energetics. Interconversion barriers are mostly smaller for H 2S complexes than for the corresponding water complexes. This is attributed in part to the size of sulfur relative to oxygen, leading to greater equilibrium separations from bonding partners and thereby decreased electrical stabilization. Values are reported for rotational constants, dipole moments, and interconversion barriers.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
