Abstract
We present structural and magnetic studies of complex [Cu(dpt)(NCS)2], 1a, dpt = bis(3-aminopropyl)amine. A weak antiferromagnetic interaction mediated by a Cu⋯ π non-covalent interaction was identified by magnetometry measurements, and the exchange magnitude (J = -2.24 cm−1, J stands for isotropic magnetic exchange constant) was determined. These results were supported by theoretical calculations (DFT) and the nature of the Cu⋯ π interaction was studied by QT-AIM. It was confirmed that the Cu⋯ π non-covalent interaction could be described as semi-coordination. The obtained results were compared to those previously reported for the isomorphous complex [Co(dpt)(NCS)2].
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
