Abstract

The core-shell [email protected]3 nanocomposites were synthesized by a facile two-step approach. The synthetic parameters on the microstructure and morphology as well as microwave absorption properties of [email protected]3 nanocomposites were investigated. High resolution transmission electron microscopy studies reveal that as-prepared [email protected]3 nanocomposites consist of the Ni nanoparticles core and polycrystalline BaTiO3 shell. The BaTiO3 coated Ni nanocomposites absorbent present significantly enhanced microwave absorption compared with the as-prepared pristine Ni nanoparticles. The optimal reflection loss (RL) of [email protected]3-parrafin composites are −42.3 dB at 10.6 GHz with an absorbent thickness of 1.88 mm and the absorption bandwidth of those below −10 dB is 6.75 GHz only with absorbent thicknesses of 1.7–2.5 mm. The RL values below −20 dB can be obtained in frequency range of 2.98–12.21 GHz for [email protected]3-parrafin composites but 7.96–14.09 GHz for Ni-paraffin composites, corresponding to absorbent layer thickness of 1.7–5.5 mm. Moreover the RL values of [email protected]3 nanocomposites absorbent exceeding −10 dB are about 1.4–3 times of those of the Ni nanoparticles absorbent at absorbent thicknesses of 1.7–5.5 mm. Furthermore, the minimum RL of [email protected]3-parrafin composite shifts to the lower frequency, compared with that of Ni-parrafin composite. These results show that microwave absorption ability of the [email protected]3 nanocomposites is superior to Ni nanoparticles and the core-shell type [email protected]3 nanocomposites are great potential microwave absorbents for practical applications.

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