Water treeing in binary linear polyethylene blends: the mechanical aspect

Abstract

Water treeing tests were performed on low density polyethylene (LDPE) and four different binary blends of sharp linear polyethylene (LPE) fractions (M/sub w/=2500 and 76000), which were either quenched in air from the melt or isothermally crystallised at 123/spl deg/C. Although the morphology and initial mechanical properties of the materials tested were significantly different, the vented tree growth characteristics were similar for all of them. This is in disagreement with the electromechanical models of water treeing, which correlate water tree growth with the fracture toughness of the material. Time to breakdown distributions were also similar for both LDPE and the binary LPE blends, which indicates that, regardless of the initial material morphology and the actual structure of water trees, the length of water trees is one of the controlling factors in insulation failure. The visible light image of water trees in LPE blends did not disappear upon drying as it usually does in LDPE and crosslinked polyethylene insulation. >