Abstract
Gel permeation chromatography is the key to isolation of pure TPPTS 1, as well as the complexes [LXMy(TPPTS)z· (H2O)3z], for which 1 serves as starting material. These complexes are of considerable interest with respect to homogeneous catalysis, since their water solubility permits them to be separated easily from hydrophobic organic reaction products. Charge concentration around the periphery of the molecule is presumably responsible for the fact that TPPTS complexes such as 2 often display lower coordination numbers than their triphenylphosphane analogues. equation image
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Angewandte Chemie International Edition in English
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
