Abstract
The values of the rate constants for the reactions of the sulfate (2.5 x 10(9) M(-1) s(-1)) and hydrogen phosphate (2.2 x 10(8) M(-1) s(-1)) radicals with silica nanoparticles are obtained by flash photolysis experiments with silica suspensions containing S(2)O(8)(2-) or P(2)O(8)(4-), respectively. The interaction of these radicals with the silica nanoparticles leads to formation of transients, probably adsorbed sulfate and hydrogen phosphate radicals, with absorption maxima at around 320 and 350 nm, respectively. A different mechanism takes place for the interaction of the less oxidizing dithiocyanate radicals with the silica nanoparticles. These radicals selectively react with the dissociated silanol groups of the nanoparticles with a rate constant at 298.2K of 7 x 10(7) M(-1) s(-1) (per mol of SiO(-) groups), and there is no evidence for their adsorption at the surface. All the results are discussed in terms of the Smoluchowski equation and redox potential of the inorganic radicals.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
