Water quality assessment and pollution source apportionment in a highly regulated river of Northeast China.

Abstract

Dams and sluices break down the river continuum, alter the river hydrological regime, and intercept the migration processes of nutrients and pollutants. The regulation of dams and sluices will have great impacts on water quality characteristics in the river basin. In this study, variable fuzzy pattern recognition model (VFPR), principal component analysis/factor analysis (PCA/FA), and the absolute principal component score-multiple linear regression (APCS-MLR) were used to assess the water quality and identify the potential pollution sources in a highly regulated river of Northeast China. A set of water quality variables at three stations were measured from January 2015 to August 2017. The water quality assessment results showed that there were spatial and temporal variations of water quality and the total nitrogen (TN) and fecal coliforms (F. coli) were the major pollution factors of the study river section. Four pollution sources, including industrial effluent source, domestic sewage source, meteorological factor and atmospheric deposition source, and agricultural non-point source, were identified in dry and wet seasons using the PCA/FA method. The APCS-MLR results showed that the industrial effluent source was the main pollution source in dry seasons and had a decrease in wet seasons. While the mean contribution of the domestic sewage source had an increase in wet seasons, influenced by the sewage overflow and the flushing of pollutants during the extreme precipitation, the construction of dams decreased the flow obviously in wet seasons and increased in dry seasons. The increase in pollutants caused by storm runoff and the reduction of dilution water in the river channel could be the main reason for the water quality degradation in wet seasons.