Abstract

A square-planar Pt(II) complex with a pyridine-based pincer-type N-heterocyclic carbene ligand, [PtII(C∧N∧C)(Cl)]Cl (C∧N∧C = 2,6-bis(1-butylimidazol-2-ylidenyl)pyridine), was synthesized as a new type of emitter and structurally characterized. The complex shows aquachromic photoluminescence in the solid state upon hydration and dehydration.

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