Abstract

In article number 2008712, Meysam Heydari Gharahcheshmeh, Karen K. Gleason, and co-workers present remarkable texture and nanostructural engineering of poly(3,4-ethylenedioxythiophene) (PEDOT) thin films grown by water-assisted oxidative chemical vapor deposition, which yields a record high electrical conductivity of 7520 S/cm. In PEDOT thin films with a highly face-on orientation, the charge transport between chains becomes a rate-limiting factor. Thus, electrical conductivity enhancement is achievable by reducing the π–π stacking distance through tuning the process parameters.

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