Water activity changes across an amphibolite-granulite facies transition, Broken Hill, Australia

Abstract

Phase compositions in pelitic and mafic gneisses place tight constraints on pressure (ranging from 3 up to 6 kb), and, to a lesser extent, on temperature (500° up to 800° C) during prograde regional metamorphism of the Willyama Complex, Broken Hill, SE Australia. These limits allow an evaluation of water activity across the terrain using various equilibria in pelitic and mafic gneisses. The stability of cummingtonite and biotite over much of the terrain places upper limits on temperature, and the presence of syn-metamorphic partial melts in the metasediments places lower limits on a(H2O). Garnet-biotitesillimanite-K feldspar-quartz relations combined with the partial melting data suggest a decrease in water activity from near 1.0 in the lower grade zones to 0.5±0.2 in the Broken Hill — Little Broken Hill part of the two pyroxene zone. This result is compatible with less precise hornblende-orthopyroxene-clinopyroxene-quartz relations.