Abstract

Aluminium dross is a hazardous industrial waste generated during aluminium production. It contains metallic oxides of aluminium and magnesium, other phases (aluminum nitride), and residues of fluxes and salts from the melting process of aluminium. Discarding this by-product is considered an environmental and economic challenge due to the high reactivity of dross with water or even air humidity. After removing the hazardous components from the as-received dross, one of the optional approaches is to incorporate the treated dross into construction materials. Dross is applied in several types of research as a secondary raw material source for alumina, clinker, cement or glass-ceramic production, but only a few papers focus on the usage of dross as a foaming agent for foams. Even fewer research are reported where dross was applied as a basic component of foam glasses. In this work, foam glasses were produced completely from waste materials: Aluminium dross, container (SLS) glass, and cathode ray tube (CRT) glass. The research holds several specificities, i.e., combining two industrial waste materials (CRT glass and dross), and adding an increased amount from the wastes. The physical and mechanical characteristics were examined with a special focus on the effect of the foam glass components on the microstructure, density, thermal conductivity, and compressive strength.

Highlights

  • Aluminium dross is a by-product of secondary aluminium melting when aluminium metal is produced from aluminium waste

  • Expanded clays and foam glasses were produced with different glass wastes and aluminium dross, where the latter acted as a foaming agent [13,14]

  • The chemical composition of the raw materials was determined as follows: The composition of SLS and cathode ray tube (CRT) glasses was determined by an X-ray fluorescence spectrometry (XRF) instrument (Rigaku SuperMini 200)

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Summary

Introduction

Aluminium dross is a by-product of secondary aluminium melting when aluminium metal is produced from aluminium waste. Dross has already been applied in several cases to produce alumina, clinker, cement or glass-ceramic materials, but only a few research used dross as a foaming agent [58] or as a basic component [10] of foamed materials. In the latter case, dross is admixed only in small amounts (2.5–5–7.5 wt%) to a soda-lime glass waste [10]. The samples were sintered in an electric chamber furnace at different temperatures (determined through the heating microscope) with a heating rate of 5 ◦C/min and a holding time of 10 min

Characterization Methods
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