Abstract

Ordinary Portland Cement is the most widely used binder in the construction sector; however, a very high carbon footprint is associated with its production process. Consequently, more sustainable alternative construction materials are being investigated, namely, one-part alkali activated materials (AAMs). In this work, waste-based one-part AAMs binders were developed using only a blast furnace slag, as the solid precursor, and sodium metasilicate, as the solid activator. For the first time, mortars in which the commercial sand was replaced by two exhausted sands from biomass boilers (CA and CT) were developed. Firstly, the characterization of the slag and sands (aggregates) was performed. After, the AAMs fresh and hardened state properties were evaluated, being the characterization complemented by FTIR and microstructural analysis. The binder and the mortars prepared with commercial sand presented high compressive strength values after 28 days of curing-56 MPa and 79 MPa, respectively. The mortars developed with exhausted sands exhibit outstanding compressive strength values, 86 and 70 MPa for CT and CA, respectively, and the other material’s properties were not affected. Consequently, this work proved that high compressive strength waste-based one-part AAMs mortars can be produced and that it is feasible to use another waste as aggregate in the mortar’s formulations: the exhausted sands from biomass boilers.

Highlights

  • Ordinary Portland Cement (OPC) is the most widely used binder in the construction sector being the basic component of mortars and concrete

  • The alkali-activated materials (AAMs) arise as a lower carbon footprint alternative provided that careful mixture design is employed in their synthesis, which can result in a carbon emission reduction of up to 50% [3]

  • Another noteworthy factor is the difference in loss on ignition (LOI) values in CA and CT compared to the reference sand, probably due to its chemical composition

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Summary

Introduction

Ordinary Portland Cement (OPC) is the most widely used binder in the construction sector being the basic component of mortars and concrete. Eco-AAMs have been developed using industrial wastes such as fly ash (FA) and granulated blast furnace slag (BFS) [4] These materials present excellent properties, namely, high mechanical strength, heat resistance, low creep, and shrinkage [5]. It is essential to develop new AAM processing methodologies, and one-part AAMs, known as the “just add water” AAM, appear to be a very promising solution. In this strategy, the precursors and the alkaline activators are used in the solid form (usually as powders) and water is added to start the geopolymerization process [7,8]. The process has obvious similitudes with the preparation of OPC-based materials

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