Abstract
Oxidation of various olefins into methylketones by a catalytic system constituted of palladium, copper, phosphomolybdovanadic acid and per(2,6-di- O-methyl)-β-cyclodextrin is investigated. The role of each redox catalytic system component is discussed from experiments under argon atmosphere and from vanadium NMR spectroscopic studies. The influence of various parameters, such as the per(2,6-di- O-methyl)-β-cyclodextrin concentration and the nature of the phosphomolybdovanadic acid is also reported. Finally, a catalytic cycle is also proposed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
