Abstract

Abstract 1. Buna-S has been vulcanized by a number of organic sulfur compounds, most interesting of which are alkylxanthogen disulfides. 2. The optimum results were obtained with a stock containing 4.00 per of ethylxanthogen disulfide, with either 2.00 per cent of N-cyclohexylbenzothiazyl-2-sulfenamide or 0.50 per cent of tetramethylthiuram disulfide. 3. The effect of small additions of t-butyl-, xylyl-, and p-methylphenylthiols was a pronounced improvement in the flex-cracking resistance of a vulcanizate containing ethylxanthogen disulfide. These observations suggest the industrial application of ethylxanthogen disulfide to alleviate some of the serious deficiencies so characteristic of Buna-S vulcanizates.

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