Volumetric studies and thermodynamics of viscous flow of hydroxamic acids in acetone + water solvent at temperatures 303.15 and 313.15 K

Abstract

Densities ρ and viscosities η of two hydroxamic acids, N-phenyl-2-chlorobenzo- and N- o-tolyl-4-chlorobenzo-, have been determined as a function of their concentration in aqueous acetone solution at temperatures 303.15 and 313.15 K. Apparent molar volumes, standard-state partial molar volumes and relative viscosities have been calculated. The viscosity data have been analyzed using Jones–Dole equation. The activation thermodynamic parameters of viscous flow have been evaluated using Feakins equation. These were obtained to throw light on the mechanism of viscous flow. Thermodynamic interactions in solutions have been studied in terms of a number of excess functions calculated from the experimental data. The effect of hydroxamic acid concentration and temperature on these parameters has been discussed. The results were interpreted in the light of solute–solvent interactions in aquo-organic media.