Volumetric properties of binary mixtures of tetrahydrofuran, dimethyl adipate, 1-butanol and 2-butanol from (288.15 to 323.15) K and modeling by Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS) models

Abstract

In this work, experimental densities data of the binary system tetrahydrofuran + 2-butanol have been determined at eight temperatures, T=(288.15–323.15) K and atmospheric pressure and used for excess molar volume calculations. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated for further non-ideal behaviour of binary mixture. Excess molar volume, VE, of experimental determined system tetrahydrofuran + 2-butanol, and four previously published binary systems, tetrahydrofuran + 1-butanol, dimethyl adipate + 1-butanol, dimethyl adipate + 2-butanol and dimethyl adipate + tetrahydrofuran were correlated with two models, Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS). In order to apply the proposed models additional data of ultrasonic speed of sounds for pure components, dimethyl adipate, tetrahydrofuran, 1-butanol and 2-butanol, were measured in the temperature range T=(288.15–323.15) K and at atmospheric pressure. Volumetric coefficients, thermal expansion coefficient α and isothermal compressibility κ were calculated from density, ultrasonic speed of sound and isobaric heat capacity data. Isobaric molar heat capacities Cp,m at all temperatures for all pure components were obtained by correlation of literature data.Both models, PFP and ERAS were used for analysis of molecular interactions present in the investigated solutions.