Abstract
Abstract The importance of the use of low temperature data with the second Szigeti relation is shown for the fluorite structure; a comparison with the NaCl and CsCl structures is given. The volume dependence of the generalized first Szigeti relation is used to calculate the Gruneisen parameter γ 1 with low temperature data; γ 1 is calculated with different models. Values of the volume dependence of the effective ionic charge are obtained independently using Hardy's model.
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