Abstract
A model is proposed for the voltammetry of metal ions in mixtures of macromolecular and simple ligands. Among other hypotheses, the model assumes excess of ligand and absence of both electrodic adsorption and kinetic effects (complexes are supposed to be totally labile or totally inert). The mathematical solution of the model provides general equations which are used for simulation purposes. Besides that, the limiting case when only 1:1 labile complexes exist is extensively discussed and the resulting equations applied to the polarographic study of the systems Zn(II) + polymethacrylic acid + phthalate and Cd(II) + polymethacrylic acid + bromide.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
