Abstract
The synthesis, characterization, and voltammetric and spectroelectrochemical investigation of [2,3,7,8,12,13,17,18-octapropyl porphyrazinato] lead(II) are reported. The characterization of newly synthesized lead porphyrazine was made by elemental analysis, 1H NMR, FT-IR, UV−vis, and MALDI-TOF. The solution redox properties and spectroelectrochemical investigation of the novel lead(II) porphyrazine were studied using various electrochemical techniques in DCM on a platinum electrode. Cyclic voltammetry and differential pulse voltammetry studies show that the complex gives two one-electron ligand-based reductions and a one-electron oxidation wave having diffusion-controlled mass transfer character. Assignments of the redox couples were confirmed by spectroelectrochemical measurements. Spectroelectrochemical studies reveal that the complex is demetalized during the controlled potential coulometry measurement after the first reduction couple of the complex.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
