Abstract
The reaction between thiuram disulphide and copper(i) perchlorate (1 : 1 molar ratio) in acetonitrile has been investigated voltammetrically with a view to arrive at a convincing mechanism of this reaction. The cyclic voltammetric study of this reaction showed the formation of a new product most plausibly copper(m) dithiocarbamate complex. Prompted by the observation that the new complex afforded analytically useful diffusion-controlled peaks at -85 to -120 mV (vs SCE) in differential pulse polarography, a new method has been developed for the microdetermination of thiuram disulphides.
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