Voltammetric sensor based on electrodeposited molecularly imprinted chitosan film on BDD electrodes for catechol detection in buffer and in wine samples.

Abstract

Phenolic compounds such as catechol are present in a wide variety of foods and beverages; they are of great importance due to their antioxidant properties. Their consumption protects against the development of certain diseases such as cancer and cardiovascular diseases. A MIP chitosan (CS) film has been electrodeposited on a boron doped diamond (BDD) electrode, by chronoamperommetry in the presence of catechol, followed by elution with 0.1M KCl. The morphology of the MIP and non-MIP (NIP) film has been studied by AFM. The electrochemical response of the sensor analyzed by cyclic voltammetry (CV) indicates that the sensor shows excellent reproducibility (RSD=4.1%) and repeatability (RSD=7.0%) for catechol detection in the range of 0 to 80μM, with a detection limit of 6.9×10-7 M and high selectivity to catechol recognition versus different phenolic compounds. The results obtained in a red wine show that it can detect catechol in a complex matrix.