Abstract

Voltammograms of thin and thick iron hydroxide layers chemically precipitated on platinum were obtained. The influence of the precipitation conditions of iron hydroxide was studied. Different types of combined potential/time perturbation programmes were employed to correlate the anodic and cathodic voltammetric peaks and to detect possible ageing-like effects. The electrochemical response of the iron hydroxide layer depends considerably on the layer thickness and precipitation conditions. The voltammetric behaviour of the precipitated iron hydroxide layer is interpreted in terms of the complex structure involving an inner poorly hydrated layer and an outer porous layer recently proposed from in situ ellipsometry data.

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