Abstract
Cyclic and rotating disc electrode voltammograms for mono- and diamino trinitrobenzenes dissolved in DMSO are presented, evaluated and discussed. The results support the presence of a stable anion radical and dianion only for the diamino derivative. The anion radical of the monoamino compound is short lived and reacts according to second order kinetics. ESR and optical spectra support this statement, allowing the identification of the anion radical of the diamino compound. The differences between both classes of trinitroaminoarene derivatives are explained as being due to the steric effect of the two bulky amino groups.
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