Volatile Mass Partitioned among the Atmosphere, Mantle, and Core in Proto-Mars

Abstract

We analyze the distribution of volatiles such as water, hydrogen, and carbon within the atmosphere, mantle, and core of Mars during its accretion stages. The partitioning of these volatiles is crucial as it influences the generation of intrinsic magnetic fields, mantle convection, and magmatic activity. The study suggests that the accretion process is responsible for the presence of water and light elements within the Martian mantle and core. We employ a hybrid-type proto-atmosphere model, which considers an upper layer composed of nebula components and a lower layer made up of degassed components from the impact degassing of the simplified building blocks based on the two-component model. Our numerical analysis implies that the formation of a magma ocean at this high temperature and pressure after around the half-size of the present Mars triggers the migration of water vapor, carbon, and hydrogen from the primordial atmosphere into the planetary interior. Ultimately, several 1021 kg of water could have been distributed to the mantle and, if degassed again by the formation of flood basalts on the Tharsis Plateau, could have supplied Mars’ ancient oceans. Meanwhile, several 1020 kg of carbon and 1019 kg of hydrogen (equivalent to 1020 kg H2O) were found to be distributed in the core. Although the distribution of sulfur was simplified so that all of the sulfur is in the core, a result of sulfur accounting for 14 wt% to 19 wt.% of the core mass would be consistent with the core density suggested by InSight.