Abstract
The relationship between the physicochemical properties of compounds and their inhibition factors of the atmospheric corrosion of steel are discussed with Schiff and Mannich bases as examples. It is shown that the inhibitive efficiency of compounds can be predicted from correlations between and calculated parameters such as saturated vapor pressure, total electron density on heteroatoms, and hydrophobicity constant. The predicted and experimental inhibition factors of new inhibitors agree to within ±10%.
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