VIZSLA-Versatile Ice Zigzag Sublimation Setup for Laboratory Astrochemistry.

Abstract

In this article, a new multi-functional high-vacuum astrophysical ice setup, VIZSLA (Versatile Ice Zigzag Sublimation Setup for Laboratory Astrochemistry), is introduced. The instrument allows for the investigation of astrophysical processes both in a low-temperature para-H2 matrix and in astrophysical analogices. In the para-H2 matrix, the reaction of astrochemical molecules with H atoms and H+ ions can be studied effectively. For the investigation of astrophysical analogices, the setup is equipped with various irradiation and particle sources: an electron gun for modeling cosmic rays, an H atom beam source, a microwave H atom lamp for generating H Lyman-α radiation, and a tunable (213-2800nm) laser source. For analysis, an FT-IR (and a UV-visible) spectrometer and a quadrupole mass analyzer are available. The setup has two cryostats, offering novel features for analysis. Upon the so-called temperature-programmed desorption (TPD), the molecules, desorbing from the substrate of the first cryogenic head, can be mixed with Ar and can be deposited onto the substrate of the other cryogenic head. The efficiency of the redeposition was measured to be between 8% and 20% depending on the sample and the redeposition conditions. The well-resolved spectrum of the molecules isolated in an Ar matrix serves a unique opportunity to identify the desorbing products of a processed ice. Some examples are provided to show how the para-H2 matrix experiments and the TPD-matrix-isolation recondensation experiments can help understand astrophysically important chemical processes at low temperatures. It is also discussed how these experiments can complement the studies carried out by using similar astrophysical ice setups.