Abstract
Azides, which are extremely rare in biological systems, are emerging as attractive chemical handles for bioconjugation.[1–5] In particular, the CuI catalyzed 1,3-dipolar cyclization of azides with terminal alkynes to give stable triazoles[6, 7] has been employed for the tagging of a variety of biomolecules,[8–12] activity-based protein profiling,[13] and the chemical synthesis of microarrays and small molecule libraries.[14]
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