Visualized adsorption and enhanced photocatalytic removal of Cr6+ by carbon dots-incorporated fluorescent nanocellulose aerogels

Abstract

In this study, carbon dots (CDs) and titanate nanofibers (TNs) were mixed with TEMPO-oxidized nanocellulose (TOCNC) to prepare fluorescent nanocellulose aerogels (FNAs) by a Schiff base reaction. The resulting FNA can detect the adsorption of Cr6+ through the fluorescence quenching in CDs and promote the removal of Cr6+ through the synergistic effect of CDs in photocatalysis. The optimized FNA has a maximum adsorption capacity of 543.38 mg/g, higher than most reported Cr6+ adsorbents. This excellent performance is due to the porous structure of the aerogel, which gives it a high specific surface area of 20.53 m2/g and provides abundant adsorption sites. Simultaneously, CDs can enhance the amino-induced Cr6+ adsorption, improve the photocatalytic performance of TNs, and expose more adsorption sites through electrostatic adsorption of amino-induced reduction products (Cr3+). This study explores the preparation of visualized nanosorbents with enhanced photocatalytic removal of Cr6+ and provides a new direction for nanoscale photocatalysts.