Visible/near Infrared Reflection Spectrometer and Electronic Nose Data Fusion as an Accuracy Improvement Method for Portable Total Soluble Solid Content Detection of Orange

Abstract

The visible/near infrared (VIS/NIR) spectrometer and electronic nose (E-nose) are two commonly used portable and nondestructive detection apparatuses which have a promising application for the quick acquisition of fruit’s internal quality in both the orchard and market. However, the accuracy of these instruments is sometimes unsatisfactory, especially for thick peeled fruit like the ‘Aiyuan 38’ orange, which was investigated in this research. The objective of this research was to find a method to improve the accuracy for the detection of an orange’s total soluble solid content (TSS) using a VIS/NIR spectrometer and E-nose. Different spectrum detection positions and conventional feature extraction methods are compared to get the optimal data fusion parameters. The detection model was then built up based on the obtained fusion data under the optimal parameters. Partial least squares regression (PLSR) and mutual information theory (MIT) were applied for feature extraction, and PLSR and principal component analysis (PCA)-back propagation neural network (BPNN) were applied for modeling and detection. PLSR results showed that the sampling reflection spectrum at the position of the calyx results in a better orange TSS detection than other sampling positions. For VIS/NIR reflection spectrum feature extraction, PLSR and MIT results showed that the optimal data process + feature extraction method is Savitzky-Golay + 763 features, when their mutual information values between the feature and TSS value were larger than 0.74. For E-nose feature extraction, PLSR and MIT results showed that the combined feature (combination of 75 s value, average value, average of differential value, integral value, and maximum value) is the optimal feature extraction method, and all features are retained for modeling. The PLSR detection ability of orange TSS based on fusion data is better than the single detection method, with the detection ability of the single detection methods being unsatisfactory. PCA-BPNN has better orange TSS detection ability than PLSR. The R2, RMSE, and slope from the calibration set for PCA-BPNN detection were 0.9695, 0.1895, and 0.9665, respectively, and from the validation set for PCA-BPNN detection were 0.8872, 0.4709, and 1.0871, respectively, indicating that this method can detect orange TSS efficiently.