Abstract
Four o- and p-nitro substituted 2-methyl-2-phenyl-2,3-dihydro-1H-perimidine derivatives were synthesized via a condensation–cyclization of naphthalene-1,8-diamine with nitro substituted acetophenones to study their photochemical properties. Only the o-nitrophenyl substituted perimidine 1 was found to be sensitive to light. When exposed to visible light under either aerobic conditions or argon atmosphere, it undergoes pyrimidine ring-opening/deoxygenation and pyrimidine oxidation to give the 2H-indazole 10 and perimidinone 11, respectively. A new visible light-sensitive o-nitrobenzylamino scaffold is introduced.
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