Abstract
Photomelting of azobenzene is a phenomenon that is typically achieved by UV-light irradiation. However, many applications based on azobenzene photomelting, including the solar thermal fuel (STF) application, require responsiveness to visible light. Therefore, in this study, we designed and synthesized several azobenzene derivatives that melt under visible-light irradiation and explored their potential application as STFs. By combining molecular design elements that endow azobenzene with visible-light-responsiveness (ortho-halogen) and photomeltability (para-alkoxy), we successfully synthesized four compounds that exhibit visible-light photomelting properties. These compounds also exhibit a long cis-isomer lifetime, which makes them good candidates for STFs in the future.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
