Visible-light-mediated metal-free C–Si bond formation reactions

Abstract

Abstract Conserving the environment is one of the most imperative goals in recent days among the chemists throughout the world. Swiftly increasing the environmental awareness also increases the demand to build new approaches for synthesizing the same active molecules with zero-waste and pollution. In this background, visible-light-mediated synthesis and functionalization of diverse organic compounds has been established as a tremendously successful topic and has achieved a remarkable stage of superiority and efficiency in the last 20 years. Alternatively, organosilicon derivatives are gradually aspiring leaves among chemists because of their significant application on synthetic, medicinal, and material chemistry. In this scenario, the addition of Si–H group to carbon−carbon multiple bonds (alkenes, hetero-arenes, alkynes, allenes, carboxylic acids, enynes, and dienes) provides an extremely step- and atom-efficient method to obtain silicon-containing compounds. Several attempts for the development of mild, robust, and efficient green protocol were taken in the last two decades. In spite of substantial advancement/research on C–Si bond formation using transition metal catalysis, a green and metal-free approach is highly essential considering its application in the field of medicine and with respect to environmental aspects as well. In this article, we will summarize the reports considering suitable visible-light-mediated metal-free silylation of C–C multiple bonds that includes alkenes, hetero-arenes, alkynes, allenes, enynes, and dienes.