Visible light-driven TiO2-WO3@GO photocatalyst with catalytic memory for round-the-clock photocatalytic degradation of oilfield-produced water

Abstract

The inability of most photocatalysts to continue the catalytic process after the removal of light irradiation is one of their major drawbacks. In this work, a ternary nanocomposite of titanium oxide (TiO2) supported with tungsten oxide (WO3) and hybridized with graphene oxide (GO) (TiO2-WO3@GO) photocatalyst with electron energy storage properties was synthesized for oilfield-produced water (OPW) treatment under visible light and in dark conditions. WO3 addition extended the light absorption range of TiO2 into the visible light while also serving as an electron storage material for dark catalysis (memory catalysis). The GO serves as an efficient electron acceptor and transporter to prevent charge carrier recombination, thereby enhancing interfacial electron transfer within the photocatalyst system. 2.5 wt%, 5 wt%, and 10 wt% of WO3 precursors were reacted with TiO2 precursor and GO was further added to synthesize the nanocomposites via a modified sol-gel and solution-based approach for the first time. The properties of the nanocomposite were assessed using a wide range of characterization. The nanocomposite containing 5 wt% WO3 showed the best photocatalytic activity with the total organic content (TOC) degradation of 27.7% within 4 h of photodegradation in visible light, which is better than 22 % in 5 h under UV light so far reported in the literature. The nanocomposite also exhibited electron energy storage properties for dark catalysis after pre-illumination, i.e., 16.6% TOC degradation in 3 h in dark conditions. This low % TOC degradation in the dark could be attributed to the complex nature of OPW. This work has further confirmed the possibility of the use of photocatalysts for dark catalysis.