Abstract
Visible light-driven benzoyl azides formation catalyzed by a rhodium ion modified TiO2 (Rh3+/TiO2) is reported. The Rh3+/TiO2 was prepared as a visible light responsive photocatalyst by a simple procedure from TiO2 and RhCl3･3H2O. The Rh3+/TiO2 exhibited a broaden visible light absorption from 400 nm to 600 nm. Benzoyl azide formation from a benzotrichloride and a trimethylsilyl azide (TMS-N3) was performed catalyzed by the Rh3+/TiO2 under visible light irradiation (λ ≥ 420 nm) in air at room temperature. In this reaction, the benzotrichloride was effectively reduced by the single electron transfer (SET) from the Rh3+/TiO2, and the benzoyl azide was produced in 71% yield via the reaction between the benzoyl chloride and TMS-N3. In addition, several benzotrichloride derivatives were applied to this reaction and the corresponding benzoyl azide derivatives were formed in up to 71% yield. A kinetic analysis was also performed on these reactions, and it was suggested that the SET is the rate determining step in this reaction.
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