Abstract
The kinematic viscosity of binary solutions methanol-n-octane at 293.15-313.15 K and ethanol-n-octane at 263.15-298.15 K in the miscibility range (low concentrations of n-octane) was measured. In the methanol-octane system, the viscosity shows an abnormal behavior. As shown by molecular-dynamic calculations, this effect is due to formation of a specific type of associates, which results in a decrease in the molecular mobility as the n-octane concentration is increased (up to the phase separation point).
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