Abstract
Influence of Nb2O5 on viscosity of the CaF2-based and CaF2-30% Al2O3-based melts was investigated using a vibration viscosimetry method in the range 1523–1873 K. It is found that viscosity of the melts rise and the crystallization range shifts to lower temperatures as the Nb2O5 concentration increases from 0 to 25 wt %. The activation energy of viscous flow increases from 34 to 110 kJ mol−1 and from 56 to 148 kJ mol−1 for the CaF2-based and CaF2-30% Al2O3-based melts, respectively. The obtained data indicate the complexing behavior of niobium in the oxide-fluoride melts.
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