Viscosity of CaO-MgO-Al2O3-SiO2-TiO2-FeO slag with varying TiO2 content: The Effect of Crystallization on Viscosity Abrupt Behavior

Abstract

Reasonable slag fluidity is essential for stable HIsmelt process operation. During the slag-tapping process, crystallization will cause the slag viscosity to rise sharply, which is not conducive to stable slag-tapping operation, especially for smelting high-titanium slag. In this paper, the viscosity of the CaO-MgO-Al2O3-SiO2-TiO2-FeO slag with varying 10–50% TiO2 content was studied in the laboratory. The crystalline phases of water quenched slag samples at different temperatures were determined by XRD, and it was verified with the results of Factsage thermodynamic calculations. In addition, the effects of crystalline phase, crystalline morphology and crystal size on the critical viscosity of slag were discussed through SEM-EDS analysis. The results show that the proper TiO2 content in the slag is below 40%, the temperature of critical viscosity (Tcv) of the slag is between 1336 °C and 1360 °C, and the Tcv of the slag with a TiO2 content of 50% increases to 1500 °C. The sudden increase in viscosity is related to the crystallization behavior of the slag. With the increase of TiO2 content, the main precipitated titanium-rich phase in the slag changed from dendritic perovskite to plate-shaped pseudobrookite. Among them, when the TiO2 content is 10%, the sharp increase in viscosity of the slag is mainly determined by the precipitation amount of melilite. The amount of crystals in the slag between 20% and 43% causes the viscosity of the slag to rise rapidly, which is mainly due to the fact that the granular crystals have a greater influence on the viscosity than the plate crystals. Compared with the experimental results, it is found that Factsage software cannot accurately calculate the phase equilibrium of slag with a TiO2 content of 40–50%.