Viscosity, heat capacity and refractive index studies for binary liquid mixtures containing 1,3-diaminopropane and alkyl acetates: Experimental and theoretical interpretation

Abstract

The viscosity (η), heat capacity (CP) and refractive index (nD) of 1,3-DAP (1,3-Diaminopropane) (1) + AAc (MAc(methyl acetate), EAc(ethyl acetate), PAc(propyl acetate) and BAc(butyl acetate)) (2) binary mixture were measured at standard ambient temperature i.e. 298.15 K under the atmospheric pressure 0.1 MPa. The data of η, CP and nD were further used to determine deviation in viscosity (Δη), excess molar heat capacity (CPE), excess Gibbs free energy of activation (G∗E), and deviation in refractive index (ΔnD). η were analyzed by Bloomfield and Dewan model (BFD). The η values were further correlated by various correlations like Kendall, Bingham, Kendall-Monroe, Arrhenius, Katti-Chaudhari, Tamura-Kurata, Grunberg-Nissan, Frenkel, Hind-McLaughlin-Ubbelohde, Heric, McAllister, Lulian, Krishnan-Laddha and Heric-Brewer. Further various correlations like Heller, Lorentz-Lorenz, Arago-Biot, Newton, Gladstone-Dale, Erying and Weiner were used to correlate nD data. The derived thermo-physical properties were also interpreted in terms of molecular interactions and correlated with Redlich- Kister polynomial equation (R.K.).